By Ramon Rios Torres
The Pauson-Khand response is a vital response within the box of natural chemistry. It contains the transition-metal catalysed cycloaddition of an alkyne, an alkene and carbon monoxide, to supply cyclopentenones. the significance of this response originates from its excessive worth in reworking basic parts into the synthetically precious cyclopentenone unit, within which a excessive measure of molecular complexity could be completed in one step, with awesome stereochemical and regiochemical keep an eye on.
The Pauson-Khand Reaction investigates the character and plenty of diversifications of this reaction.
Topics lined include:
- the mechanisms of Pauson‐Khand-type reactions
- non chiral intramolecular and intermolecular types of Pauson‐Khand reactions
- asymmetric Pauson‐Khand response utilizing chiral auxiliaries
- the enantioselective Pauson‐Khand reaction
- Pauson‐Khand reactions catalysed via metals except cobalt
- unconventional Pauson‐Khand reactions
- the Pauson‐Khand response in overall synthesis
Presenting a finished evaluation of this basic response, The Pauson-Khand Reaction will discover a position at the bookshelves of any natural or organometallic chemist.
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