The 1st version of this booklet have been written with the distinct objective to supply the required details for an figuring out of the deformation and scission of chain molecules and its position in polymer fracture. during this box there were an excessive ac tivity within the sixties and early seventies. the hot effects from spectroscopical (ESR, IR) and fracture mechanics equipment mentioned within the first version had complemented in a truly winning approach the normal interpretations of fracture habit. The super pleasant reception of this publication by means of the polymer neighborhood has proven that the topic was once well timed selected and that the therapy had chuffed a necessity. In view of the significance of a molecular interpretation of fracture phenomena and of the continuing call for for this ebook which nonetheless is the single one in all its sort, a moment variation has develop into precious. The goals of the second one variation could be just like these of the 1st: will probably be at tempted to reference and overview thoroughly the literature on stress-induced chain scission, now as much as 1985/86. References on different matters similar to morphology, vis coelasticity, plastiC deformation and fracture mechanics, the place the therapy was once by no means intended to be exhaustive, have remained selective, yet they've been up-to-date.
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