By K. Alder, J. Asselineau, A. Chatterjee, L. Feinstein, M. Jacobson, E. Lederer, H. Mark, G. Rosenkranƶ, M. Schumacher, F. Sondhei
Read Online or Download Fortschritte der Chemie Organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products / Progres dans La Chimie des Substances Organiques Naturelles PDF
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Extra resources for Fortschritte der Chemie Organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products / Progres dans La Chimie des Substances Organiques Naturelles
The cyanogenic glycosides, the following outlined as glycosidic derivatives of iX-hydroxynitriles, characterize a slightly constrained classification of common items, that are largely dispensed within the plant country and, to a small ex tent, even in animals. A attribute function of those glycosides is their skill to unencumber hydrocyanic acid on therapy with dilute acids or acceptable enzymes. The time period "cyanogenic" is used to designate this estate, whether natural ingredients, vegetation, or animals, are serving because the resource. within the latter instances the time period "cyanophoric" is sometimes hired synonymously. Cyanogenesis in vegetation was once most likely first found via SCHRADER in 1803 (Io3) operating with sour almonds. In 1830, ROBIQUET and BOUTRON-CHARLARD (IOO) succeeded in setting apart the mother or father glycoside, particularly amygdalin. through the years, a complete of 18 cyanogenic glycosides were remoted and characterised roughly thoroughly (Table I, p. 76). will probably be famous that most of those compounds has been remoted within the period of classical natural chemistry and that development in .discovering new compounds, let alone new structural forms, has been unusually gradual. it really is worthy remembering the following that the mechanism ·of cyanogenesis has been validated simply within the minority of recognized cyanogenic species. The cyanogenic glycosides have final been reviewed in 1958 by means of DILLE MANN (36). seeing that then, no whole reports during this box have seemed. it's the goal of the current article to survey the more moderen advert vances and, with a bit of luck, to stimulate endured curiosity in those fascinating .compounds.
The volumes of this vintage sequence, now said easily as 'Zechmeister' after its founder, L. Zechmeister, have seemed below the Springer Imprint ever because the sequence' inauguration in 1938. The volumes include contributions on numerous issues with regards to the starting place, distribution, chemistry, synthesis, biochemistry, functionality or use of varied periods of certainly happening components starting from small molecules to biopolymers. each one contribution is written by way of a well-known authority in his box and offers a entire and updated assessment of the subject in query. Addressed to biologists, technologists, and chemists alike, the sequence can be utilized via the professional as a resource of data and literature citations and through the non-expert as a way of orientation in a quickly constructing self-discipline.